Mineralogical siting of platinum-group elements in pentlandite from the Bushveld Complex,South Africa     

Malte Junge  Richard Wirth  Thomas Oberthür  Frank Melcher  Anja Schreiber 《Mineralium Deposita》2015,50(1):41-54

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Upstairs-downstairs: supercontinents and large igneous provinces,are they related?     

Kent C. Condie  Anne Davaille  Richard C. Aster  Nicholas Arndt 《International Geology Review》2015,57(11-12):1341-1348

There is a correlation of global large igneous province (LIP) events with zircon age peaks at 2700, 2500, 2100, 1900, 1750, 1100, and 600 and also probably at 3450, 3000, 2000, and 300 Ma. Power spectral analyses of LIP event distributions suggest important periodicities at 250, 150, 100, 50, and 25 million years with weaker periodicities at 70–80, 45, and 18–20 Ma. The 25 million year periodicity is important only in the last 300 million years. Some LIP events are associated with granite-forming (zircon-producing) events and others are not, and LIP events at 1900 and 600 Ma correlate with peaks in craton collision frequency. LIP age peaks are associated with supercontinent rifting or breakup, but not dispersal, at 2450–2400, 2200, 1380, 1280, 800–750, and ≤200 Ma, and with supercontinent assembly at 1750 and 600 Ma. LIP peaks at 2700 and 2500 Ma and the valley between these peaks span the time of Neoarchaean supercraton assemblies. These observations are consistent with plume generation in the deep mantle operating independently of the supercontinent cycle and being controlled by lower-mantle and core-mantle boundary thermochemical dynamics. Two processes whereby plumes can impact continental assembly and breakup are (1) plumes may rise beneath supercontinents and initiate supercontinent breakup, and (2) plume ascent may increase the frequency of craton collisions and the rate of crustal growth by accelerating subduction.  相似文献   

Timing of porphyry (Cu-Mo) and base metal (Zn-Pb-Ag-Cu) mineralisation in a magmatic-hydrothermal system—Morococha district,Peru     

Honza Catchpole  Kalin Kouzmanov  Aldo Bendezú  Maria Ovtcharova  Richard Spikings  Holly Stein  Lluís Fontboté 《Mineralium Deposita》2015,50(8):895-922

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Experimental petrology constraints on the recycling of mafic cumulate: a focus on Cr-spinel from the Rum Eastern Layered Intrusion,Scotland     

Julien?LeutholdEmail author  Jonathan?D.?Blundy  Richard?A.?Brooker 《Contributions to Mineralogy and Petrology》2015,169(2):12

The ¹⁷⁶Lu–¹⁷⁶Hf and ¹⁴⁷Sm–¹⁴³Nd decay systems are routinely used to determine garnet (Grt)–whole-rock (WR) ages; however, the ¹⁷⁶Lu–¹⁷⁶Hf age of garnet is typically older than the ¹⁴⁷Sm–¹⁴³Nd age determined from the same aliquots. Here we present experimental data for Lu³⁺ and Hf⁴⁺ diffusion in garnet as functions of temperature, pressure and oxygen fugacity and show that the diffusivity of Hf⁴⁺ in almandine/spessartine garnet is significantly slower than that of Lu³⁺. The diffusive closure temperature (T _C) of Hf⁴⁺ is significantly higher than that of Nd³⁺, and although this property is partly responsible for the observed ¹⁷⁶Lu–¹⁷⁶Hf and ¹⁴⁷Sm–¹⁴³Nd Grt–WR age discrepancies, the difference between the T _C-s of Lu³⁺ and Hf⁴⁺ could lead to apparent Grt–WR ¹⁷⁶Lu–¹⁷⁶Hf ages that are skewed from the age of Hf⁴⁺ closure in garnet. In addition, the slow diffusivity of Hf⁴⁺ indicates that the bulk of metamorphic garnets retain a substantial fraction of prograde radiogenic ¹⁷⁶Hf throughout peak metamorphic conditions, a phenomenon that further complicates the interpretation of ¹⁷⁶Lu–¹⁷⁶Hf garnet ages and invalidates the use of analytical T _C expressions. We argue that the diffusion of trivalent rare earth elements in garnet becomes much faster when their concentration level falls below a few hundred ppm, as in the experiments of Tirone et al. (Geochim Cosmochim Acta 69: 2385–2398, 2005), and further argue that this low-concentration mechanism is appropriate for modeling the susceptibility of ¹⁴⁷Sm–¹⁴³Nd garnet ages to diffusive resetting.  相似文献   

Interplay between an axial channel belt,slope gullies and overbank deposition in the Puchkirchen Formation in the Molasse Basin,Austria          下载免费PDF全文

Larisa U. Masalimova  Donald R. Lowe  Timothy Mchargue  Richard Derksen 《Sedimentology》2015,62(6):1717-1748

Deep‐water sediments in the Molasse Basin, Austria, were deposited in a narrow foreland basin dominated by a large channel belt located between the steep Alpine fold and thrust belt to the south and the gentler northern slope off the Bohemian Massif. Several gas fields occur outside the channel belt, along the outer bend of a large meander. Accumulation of these overbank sediments reflects a complicated interplay between slope accommodation and debris‐flow and turbidity‐flow interaction within the channel. The tectonically oversteepened northern slope of the basin (ca 2 to 3°) developed a regionally important erosional surface, the Northern Slope Unconformity, which can be traced seismically for >100 km in an east–west direction and >20 km from the channel to the north. The slope preserves numerous gullies sourced from the north that eroded into the channel belt. These gullies were ca 20 km long, <1 km wide and ca 200 m deep. As the channel aggraded, largely inactive and empty gullies served as entry points into the overbank area for turbidity currents within the axial channel. Subsequently, debris‐flow mounds, 7 km wide and >15 km long, plugged and forced the main channel to step abruptly ca 7 km to the south. This resulted in development of an abrupt turn in the channel pathway that propagated to the east and probably played a role in forming a sinuous channel later. As debris‐flow topography was healed, flows spread out onto narrow area between the main channel and northern slope forming a broad fine‐grained apron that serves as the main gas reservoir in this area. This model of the overbank splay formation and the resulting stratigraphic architecture within the confined basin could be applied in modern and ancient systems or for subsurface hydrocarbon reservoirs where three‐dimensional seismic‐reflection data is limited. This study elucidates the geomorphology of the oversteepened slope of the under‐riding plate and its effects on the sedimentation.  相似文献   

Temporal association of arc–continent collision,progressive magma contamination in arc volcanism and formation of gold-rich massive sulphide deposits on Wetar Island (Banda arc)     

Richard J. Herrington  Philip M. Scotney  Stephen Roberts  Adrian J. Boyce  Darrell Harrison 《Gondwana Research》2011,19(3):583-593

Whole-rock ⁸⁷Sr/⁸⁶Sr and δ¹⁸O analyses of volcanic rocks and ³He/⁴He analyses of sulphides and sulphates from mineralized rocks on Wetar, Indonesia indicate a variable contribution of assimilated crustal material or sediment sourced from the subducted Australian craton to the south. These new data support the idea of progressive source contamination with precisely dated events showing that Wetar Island hosts the most extreme examples of crustal assimilation in the region. The increased continental contamination occurs during the Pliocene (Zanclian to Piacenzian) during distinct magmatic events between 5 and 4 Ma, and at 2.4 Ma when ⁸⁷Sr/⁸⁶Sr ratios in unaltered lavas, with whole-rock δ¹⁸O values between 5.7 and 9.6‰, increase from 0.707484 to extreme radiogenic values of 0.711656.The earlier of these magmatic events is important in the generation of the hydrothermal systems responsible for the mineralization recorded on Wetar. Samples from this yield radiogenic ³He/⁴He ratios between 0.5 and 1.4 R/R_A, similar to the data from volcanic rocks on nearby Romang. The later magmatic event coincides with the arrival of the Australian Continental Margin at the subduction zone along the Banda arc. Progressive incorporation of continental-sourced components into the source region below the Wetar Island edifice coincides with the formation of gold-rich volcanogenic massive sulphide deposits hosted within the contaminated volcanic pile.  相似文献   

Erratum to: Comparison of quantitative petrographic, stable isotope and cathodoluminescence data for fingerprinting Czech marbles     

Aneta ?t’astná  Richard P?ikryl  Alena ?erníková 《Environmental Earth Sciences》2011,64(4):1195-1196

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Comparison of quantitative petrographic, stable isotope and cathodoluminescence data for fingerprinting Czech marbles   总被引：1，自引：1，他引：0  

Aneta Šťastná  Richard Přikryl  Alena Černíková 《Environmental Earth Sciences》2011,63(7-8):1651-1663

Various marbles from both historic quarries and historical artefacts of the Czech Republic were examined in order to make determinations of their provenance. The methodology used was based upon a combination of petrographic image analysis (PIA) of thin sections, stable isotope geochemistry of carbonates, and cathodoluminescence. Multivariate statistical methods (i.e. cluster analysis and discriminant analysis) confirmed the geoscientific relevance of the marble’s different characteristics with a high degree of consistency as well as the enhanced significance of stable C and O isotopes in correlation with the petrographic data. The qualitative cathodoluminescence data provided a useful additional tool to help recognise the fingerprinting of marbles with similar petrographic and/or geochemical characteristics.  相似文献   

Pravčice Rock Arch (Bohemian Switzerland National Park, Czech Republic) deterioration due to natural and anthropogenic weathering     

Zuzana Vařilová  Richard Přikryl  Václav Cílek 《Environmental Earth Sciences》2011,63(7-8):1861-1878

The dominant factors affecting the development of weathering forms on the Prav?ice Rock Arch (PRA) (Bohemian Switzerland National Park, Czech Republic) are discussed, based on the in situ monitoring of weathering forms, as well as on laboratory studies of materials taken from this site. The in situ monitoring shows the progressive development of distinct weathering forms (delamination of case-hardened rock surfaces, cyclic efflorescence, and granular disintegration of exposed weakly cemented rock mass) in specific portions of the PRA, whose location is controlled by lithology, jointing/local hydrodynamics, and exposure to climatic factors. From the analysis of efflorescence, the dominance of sulphates is evident; particularly of gypsum and alums. However, the synergistic effects of the several salt species (that also include minor nitrates and chlorides) upon the mechanical disintegration of sandstone can be expected.  相似文献   

Particle fluxes in San Pedro Basin, California: A four-year record of sedimentation and physical forcing     

Lisa E. Collins  William BerelsonDouglas E. Hammond  Angela Knapp  Richard SchwartzDoug Capone 《Deep Sea Research Part I: Oceanographic Research Papers》2011,58(8):898-914

Moored sediment traps were deployed from January 2004 through December 2007 at depths of 550 and 800 m in San Pedro Basin (SPB), CA (33°33.0′N, 118°26.5′W). Additionally, floating sediment traps were deployed at 100 and 200 m for periods of 12-24 h during spring 2005, fall 2007, and spring 2008. Average annual fluxes of mass, particulate organic carbon (POC), ??¹³C_org, particulate organic nitrogen (PON), ??¹⁵N-PON, biogenic silica (bSiO₂), calcium carbonate (CaCO₃), and detrital material (non-biogenic) were coupled with climate records and used to examine sedimentation patterns, vertical flux variability, and organic matter sources to this coastal region. Annual average flux values were determined by binning data by month and averaging the monthly averages. The average annual fluxes to 550 m were 516±42 mg/m² d for mass (sdom of the monthly averages, n=117), 3.18±0.26 mmol C/m² d for POC (n=111), 0.70±0.05 mmol/m² d for CaCO₃ (n=110), 1.31±0.21 mmol/m² d for bSiO₂ (n=115), and 0.35±0.03 mmol/m² d for PON (n=111). Fluxes to 800 and to 550 m were similar, within 10%. Annual average values of ??¹³C_org at 550 m were −21.8±0.2‰ (n=108), and ??¹⁵N averages were 8.9±0.2‰ (n=95). The timing of both high and low flux particle collection was synchronous between the two traps. Given the frequency of trap cup rotation (4-11 days), this argues for particle settling rates ≥83 m/d for both high and low flux periods. The moored traps were deployed over one of the wettest (2004-2005, 74.6 cm rainfall) and driest (2006-2007, 6.6 cm) rain years on record. There was poor correlation (Pearson's correlation coefficient, 95% confidence interval) of detrital mass flux with: C_org/N ratio (r=0.10, p=0.16); ??¹⁵N (r=−0.19, p=0.02); and rainfall (r=0.5, p=0.43), suggesting that runoff does not immediately cause increases in particle fluxes 15 km offshore. ??¹³C_org values suggest that most POC falling to the basin floor is marine derived. Coherence between satellite-derived chlorophyll a records from the trap location (±9 km² resolution) and SST data indicates that productivity and export occurs within a few days of upwelling and both of these parameters are reasonable predictors of POC export, with a time lag of a few days to 2 weeks (with no time lag—SeaWiFS chlorophyll a and POC flux, r=0.25, p=0.0014; chlorophyll a and bSiO₂ flux, r=0.28, p=0.0002).  相似文献